MATERIAL SAFETY DATA SHEET

SAFETY DATA SHEET according to Regulation (EU) 2020/878
                                                                            
PRODUCT: PROTECTORGLAZE

1.  IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product Identifier
PRODUCT NAME:        PROTECTORGLAZE PEELABLE COATING

1.2 Relevant identified uses of the substance or mixture and uses advised against
PRODUCT USE: (SU22) Professional uses: Public domain (administration, education, entertainment, services, craftsmen); (PC9a) Coatings & paints, thinners, paint removers; (PROC 7) Industrial spraying  

DESCRIPTION: One-pack performance coatings

1.3 Suppliers of the safety data sheet
COMPANY: ProtectorGlaze Ltd, 47 The Hollins, Calverton, Nottinghamshire, NG14 6JR
                    Web: www.protectorglaze.com Tel: 0800 707 6711 Email: sales@protectorglaze.com

1.4 Emergency Contact Number
      Tel: 0800 707 6711 or 07834 478593

2. HAZARDS IDENTIFICATION

Water Based and not regarded as a health or environmental hazard under current legislation. 

EC 1272/2008 Skin Sens 1: H317 – May cause an allergic skin reaction

P261 – Avoid breathing dust/fume/gas/mist/vapours/spray
P272 – Contaminated work clothing should not be allowed out of the workplace
P280 – Wear protective gloves/protective clothing/eye protection/face protection
P302+P352 - IF ON SKIN: Wash with plenty of water. 
P321 - Specific treatment (see on this label). 
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P501 - Dispose of contents/container to an appropriate waste site or reclaim (in accordance with 
         local/regional/national/international regulation).

3.  COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients are not hazardous and not regulated.

EC 1272/2008

Chemical Name                     Cas No.       EC No.      REACH Reg No.    Conc (%w/w)    Classification
Sodium Petroleum 
Sulphanate                           68608-26-4   271-781-5   01-2119527859-22    1-10%          Eye Irrit. 2: H319

Distillates (Petroleum)
Hydrotreated Naphthenic     64742-52-5    265-155-0                                         1-10%         Asp. Tox. 1: H304

1,2 Benzisothiazol-3 (2H)     2634-33-5                                                                 0-0.5%        Acute. Tox. 4: H302
                                                                                                                                         Skin Irrit. 2: H315
                                                                                                                                         Skin Sens 1: H317
                                                                                                                                         Eye Dam 1: H318
                                                                                                                                         Acute Tox. 2: H330
                                                                                                                                     Aquatic Acute 1: H400
                                                                                                                                    AquaticChronic2:H411

2, methyl-4isothyazolin-2-one 2682-20-4    220-239-6                               0-0.5%          Acute Tox. 3: H301
                                                                                                                                         Skin Corr 1B: H314
                                                                                                                                         Skin Sens 1:  H317
                                                                                                                                         Eye Dam 1:   H318
                                                                                                                                         Acute Tox 1:  H330
                                                                                                                                     Aquatic Acute 1: H400
                                                                                                                                   AquaticChronic2: H411

Benzotriazole Derivative   607-176-00-3   400-830-7     01-2119396032-43    0-0.5%     Skin Sens, 1: H317
                                                                                                                                          Aquatic Chronic 2:
                                                                                                                                          H411 
Kerosine – unspecified
Distillates                          649-422-00-2    64742-47-8                                     0-0.5%     Asp.Tox 1: H304                    

4. FIRST AID MEASURES

4.1 Description of first aid measures
SKIN CONTACT:	Frequent or prolonged skin contact may irritate skin.
EYE CONTACT:	Slightly irritating but does not injure eye tissue.
INHALATION:	Vapours may be irritating to respiratory system and nasal passages.
INGESTION:	Low toxicity.  No hazard with normal use.
CHRONIC:	None known.

4.2 Most important symptoms and effects, both acute and delayed
SKIN CONTACT: May cause allergic reactions in susceptible people
EYE CONTACT:  No significant hazard
INHALATION: No significant hazard
INGESTION: No significant hazard
CHRONIC: None Known

4.3 Indication of any immediate medical attention and special treatment needed
SKIN CONTACT: Seek medical attention if irritation or symptoms persist
EYE CONTACT: Seek medical attention if irritation or symptoms persist
INHALATION: Seek medical attention if irritation or symptoms persist
INGESTION: Seek medical attention if irritation or symptoms persist

5. FIRE FIGHTING MEASURES

5.1 Extinguishing Media 
This product is non-flammable. Use fire-extinguishing media appropriate for surrounding 
materials.

5.2 Special hazards arising from the substance or mixture
Burning may produce irritating or obnoxious fumes

5.3 Advice for Firefighters
Wear suitable respiratory equipment if deemed necessary

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal Precautions
Wear protective clothing as described in Section 8 of this safety data sheet.

6.2 Environmental Precautions
Do not allow to enter drains, sewers or watercourses. Contain spillages with sand, earth or any 
suitable absorbent material. Transfer liquid to containers, if possible, for recovery or disposal.

6.3 Methods for material containment and cleaning up 
Flush away spillage with plenty of water. Spill emulsion very slippery. Avoid falls.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Avoid spilling, skin and eye contact. Do not use in confined spaces without adequate ventilation and/or respirator.

7.2 Conditions for safe storage including any incompatibilities
Keep containers tightly closed. Keep in original container. Keep away from food, drink and animal feeding stuffs. Store above freezing, ideally between 5 -25 deg C. Minimise contact with air to prevent bacterial growth. Store in original containers.

7.3 Specific End Use
See section 1.2 for further information.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

DNEL: Derived no-effect level.

Exposure pattern - Workers
Benzotriatole derivative              Long-term – inhalation - local effects 0.398 <none> 
                                                   Long-term – dermal – local effects 0.25 <none>

Exposure pattern – General public
Benzotriatole derivative              Long-term – inhalation – local effects 0.099 <none>   
                                                   Long-term – dermal – local effects 0.025 <none>  
                                                   Long-term – oral – systemic effects 0.025 <none>   

8.2 Exposure Controls

8.2.1 Appropriate engineering controls 
Ensure adequate general ventilation within the work area

8.2.2 Individual protection measures

HAND PROTECTION
Wear protective gloves.

EYE PROTECTION
Wear approved safety goggles.

RESPIRATORY PROTECTION 
Do not breather spray for prolonged periods. 
In case of insufficient ventilation, wear suitable respiratory equipment

HYGIENE MEASURES 
Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact
Wash at the end of every work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes wet. When using do not eat, drink or smoke.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on physical appearance and chemical properties

APPEARANCE:                       White Viscous Aqueous Liquid

COLOUR:                                White (Dries and cures clear)

ODOUR:                                  Mild odour

RELATIVE DENSITY:             1.02 (H2O 1 @ 20deg C) 

VISCOSITY:                            10000 mPas (Cone & Plate) 

FLASH POINT (DEG C):         N/A

EXTINGUISHING MEDIA:       N/A

EVAPORATION RATE            As per water

SOLUBILITY IN WATER         100%

TENSILE STRENGTH             >5Mpa

ELONGATION                         >1000% 

ADHESION                              <1.0MPa 

SOLIDS CONTENT                  Approximately 45%

Ph   (Neat)                                Approximately 7-8

FIRE FIGHTING PROCEDURES: This product is non-flammable and does not cause hazard.

9.2 Other Information
CONDUCTIVITY                      NO DATA AVAILABLE
SURFACE TENSION               NO DATA AVAILABLE
SPECIFIC GRAVITY                1.02G/CM3
GAS GROUP                           NO DATA AVAILABLE
BENZENE CONTENT             0%
LEAD CONTENT                     0%
VOC                                         0g/l

10. STABILITY AND REACTIVITY

10.1 Chemical Stability
Stable under normal temperature conditions and recommended use.
10.2 Reactivity
No Significant Hazard
10.3 Possibility of Hazardous Reactions
None known
10.4 Conditions to Avoid
No Significant Hazard

10.5 Incompatible materials
None known
10.6 Hazardous decomposition products
Burning can produce irritating and obnoxious fumes

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
INHALATION
May cause irritation to the respiratory system.

INGESTION
May cause discomfort if swallowed.

SKIN CONTACT
Liquid may irritate skin.

EYE CONTACT
Splashes may irritate

11.1.4 Toxicological Information
Benzotriazole Derivative       Dermal Rat LD50: > 2000mg/kg        Oral Rat LD50: >5000mg/kg
                                                 Inhalation Rat LD50/4h: >5.8mg/L

ProtectorGlaze Peelable
Coating                                     Dermal Rat LD50: >5000mg/kg        Oral Rat LD50: >10000mg/kg
                                                 Dermal Rabbit LD50: >5000mg/kg

12. ECOLOCICAL INFORMATION

12.1 Toxicity
No Data Available

12.2 Persistence & Degradability
No observed effect level

12.3 Bioaccumulate potential
No observed effect level
Partition coefficient
ProtectorGlaze – No data available

12.4 Mobility in soil
No observed effect level

12.5 Results of PBT & vPvB assessment 
No significant hazard

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Dispose of in compliance with all regional and national regulations

14. TRANSPORT INFORMATION

14.1 UN Number
The product is not classified as hazardous by international regulation on the transport of dangerous goods 
(IMDG, IATA, ADR, RID)

14.2 UN Proper shipping name
Non required

14.3 Transport hazard classes
Not classified

14.4 Packing group
Not classified

14.5 Environmental hazards
Not classified

14.6 Special precautions for user
Not classified

14.7 Transporting in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not classified

COMMODITY CODE: 3905999099

15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2 Chemical safety assessment
No data available 

16. OTHER INFORMATION

Other information

Text of Hazard Statements in Section 3

Eye Irritation. 2:  H319: Can cause eye irritation
Acute Tox. 4: H302 Harmful if swallowed
Skin Irrit. 2: H315 Can cause skin irritation
Skin Sens. 1: H317 May cause an allergic skin reaction
Eye Dam. 1: H318 Can cause serious eye damage
Acute Tox. 2: H330 Can be fatal if inhaled
Aquatic Acute. 1: H400 Toxic to aquatic life
Aquatic Chronic. 2: H411 Toxic to aquatic life with lasting effects
Acute Tox. 3: H301 Toxic if swallowed
Skin Corr. 1B: H314 Can cause severe skin burns and eye damage
Acute Tox. 1: H330 Can be fatal if inhaled
EUH208 – Contains. May produce an allergic reaction
Asp. Tox. 1: H304 May be fatal if swallowed and enters airways

Maximum content of VOC 0g/l

REVISION DATE:  MARCH 2023
REVIEW DATE: MARCH 2025 (OR AS REQUIRED.)

DISCLAIMER

Information presented herein has been compiled from information provided to us by our suppliers and other sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief but it is not guaranteed to be so.  Nothing herein is to be construed as recommending any practice or the use of any product in violation of any patent of in violation of any law or regulation.   It is the user’s responsibility to determine the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary.  We make no warranty as to the results to be obtained in using any material and, since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us.